(Bio)chemical sediments as geochemical archives through deep time - Nutrient availability and the co-evolution of Earth's oceans, atmosphere, continents, and life
Bio-essential elements such as P, N, Ni, Mo, Cd, Zn Co, Fe, and other trace metals may have played different but major roles as nutrients over geologic timescales. Their bioavailability is therefore critical in primary production, with significant implications for C and O cycles and, eventually, the evolution of life. However, there is ongoing disagreement about the conflicting role of some nutrients in early Earth's primary production. Despite collective efforts, major questions remain on how and why some elements became essential to building biomolecules, what controlled their provision to living organisms, and how different continental and atmospheric configurations contributed to this development. Aquatic (bio)chemical sediments such as carbonates, lithified microbial mats (microbialites and stromatolites), phosphates, cherts, and banded iron formations are abundant throughout Earth's history and may hold the key to studying the long-term evolution of dissolved bio-essential nutrients and interactions of the biosphere-atmosphere-hydrosphere systems with the geodynamical evolution of the Earth. Geochemical analyses of such archives are critical for extracting information on environmental conditions, geomicrobiological cycles, and post-depositional alteration in modern and ancient systems from natural materials' chemical and isotopic composition. We invite submissions that utilize geochemical and modeling, sedimentological and experimental approaches over a range of natural environments to address these questions and better understand the co-evolution of nutrients and other elemental supplies on Earth's habitats through deep time.